Benzene → Phenylthionophosphonic dichloride

Reaktionsgleichung

[P:1]([Cl:5])(Cl)([Cl:3])=[S:2].[CH:6]1[CH:11]=[CH:10][CH:9]=[CH:8][CH:7]=1>>[C:6]1([P:1]([Cl:5])([Cl:3])=[S:2])[CH:11]=[CH:10][CH:9]=[CH:8][CH:7]=1

Komponenten

Edukt 2

HCID 241Benzene

HCID 19883Thiophosphoryl chloride

Produkt 1

HCID 19016Phenylthionophosphonic dichloride

Reaktionsbedingungen

Temperatur: 200 °C

Versuchsvorschrift

In a 100 cc autoclave, 42.35 g (0.25 mole) of thiophosphoryl trichloride, 19.53 g (0.25 mole) of benzene were charged, and the mixture was heated with stirring at 200° C for 4 hours. The reaction mixture was treated in accordance with the process of Example 1. No phenylphosphonothioic dichloride was produced.

Aufarbeitung

temperaturethe mixture was heated
additionThe reaction mixture was treated in accordance with the process of Example 1

Quellen und Nachweise

ORD-Eintrag: ord-3415756249a948d698066d8c2ad191f4
Quelldatensatz: uspto-grants-1976_10
DOI: 10.6084/m9.figshare.5104873.v1
Patentnummer: US03988368

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