Diphenyliodonium chloride → Diphenyliodonium tetrakis(pentafluorophenyl)borate

HRID 129651Notizen

Reaktionsgleichung

Reaktionsgleichung von HRID 129651
[Cl-].[C:2]1([I+:8][C:9]2[CH:14]=[CH:13][CH:12]=[CH:11][CH:10]=2)[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=1.[F:15][C:16]1[C:21]([B-:22]([C:45]2[C:50]([F:51])=[C:49]([F:52])[C:48]([F:53])=[C:47]([F:54])[C:46]=2[F:55])([C:34]2[C:39]([F:40])=[C:38]([F:41])[C:37]([F:42])=[C:36]([F:43])[C:35]=2[F:44])[C:23]2[C:28]([F:29])=[C:27]([F:30])[C:26]([F:31])=[C:25]([F:32])[C:24]=2[F:33])=[C:20]([F:56])[C:19]([F:57])=[C:18]([F:58])[C:17]=1[F:59].[Li+]>O>[F:51][C:50]1[C:45]([B-:22]([C:23]2[C:28]([F:29])=[C:27]([F:30])[C:26]([F:31])=[C:25]([F:32])[C:24]=2[F:33])([C:21]2[C:20]([F:56])=[C:19]([F:57])[C:18]([F:58])=[C:17]([F:59])[C:16]=2[F:15])[C:34]2[C:35]([F:44])=[C:36]([F:43])[C:37]([F:42])=[C:38]([F:41])[C:39]=2[F:40])=[C:46]([F:55])[C:47]([F:54])=[C:48]([F:53])[C:49]=1[F:52].[C:9]1([I+:8][C:2]2[CH:3]=[CH:4][CH:5]=[CH:6][CH:7]=2)[CH:10]=[CH:11][CH:12]=[CH:13][CH:14]=1

Komponenten

4

Edukt 2

HCID 73870Diphenyliodonium chlorideHCID 23709652Lithium tetrakis(pentafluorophenyl)borate

Produkt 1

HCID 21918056Diphenyliodonium tetrakis(pentafluorophenyl)borateAusbeute 75 %

Reagenzien, Katalysatoren, Lösungsmittel 1

HCID 962WaterLösungsmittel2×

Versuchsvorschrift

7.17 g (or 22.6 mmol) of diphenyliodonium chloride were dissolved in 300 ml of water in a 1,000 ml Erlenmeyer flask. 15.52 g (or 22.6 mmol) of lithium tetrakis(pentafluorophenyl)borate in solution in 250 ml of water were added dropwise. The mixture was maintained under stirring for 30 minutes and was then filtered. The filtrate was dried under reduced pressure (133 Pa) overnight with the exclusion of light. 16.33 g (or a yield of 75%) of diphenyliodonium tetrakis(pentafluorophenyl)borate were thus recovered.

Aufarbeitung

  1. temperatureThe mixture was maintained
  2. filtrationwas then filtered
  3. customThe filtrate was dried under reduced pressure (133 Pa) overnight with the exclusion of light
  4. custom16.33 g (or a yield of 75%) of diphenyliodonium tetrakis(pentafluorophenyl)borate were thus recovered

Quellen und Nachweise

ORD-Eintrag
ord-6384164cd22146bd8e8ee6bce72735ff
Quelldatensatz
uspto-grants-1995_11
Patentnummer
US05468902

Notizen zur Reaktion

Wird geladen…