Zinc Nitrate → ZINC bis(2,4,6-tris(dimethylaminomethyl)phenolate)

HRID 129904Notizen

Reaktionsgleichung

Reaktionsgleichung von HRID 129904
[CH3:1][N:2]([CH2:4][C:5]1[CH:10]=[C:9]([CH2:11][N:12]([CH3:14])[CH3:13])[CH:8]=[C:7]([CH2:15][N:16]([CH3:18])[CH3:17])[C:6]=1[O-:19])[CH3:3].[Na+].[N+]([O-])([O-])=O.[Zn+2:25].[N+]([O-])([O-])=O>C(O)CCC>[CH3:3][N:2]([CH2:4][C:5]1[CH:10]=[C:9]([CH2:11][N:12]([CH3:13])[CH3:14])[CH:8]=[C:7]([CH2:15][N:16]([CH3:18])[CH3:17])[C:6]=1[O-:19])[CH3:1].[CH3:3][N:2]([CH2:4][C:5]1[CH:10]=[C:9]([CH2:11][N:12]([CH3:13])[CH3:14])[CH:8]=[C:7]([CH2:15][N:16]([CH3:18])[CH3:17])[C:6]=1[O-:19])[CH3:1].[Zn+2:25]

Komponenten

4

Edukt 2

HCID 24518Zinc NitrateHCID 23711567Sodium 2,4,6-tris(dimethylaminomethyl)phenolate

Produkt 1

HCID 67805255ZINC bis(2,4,6-tris(dimethylaminomethyl)phenolate)

Reagenzien, Katalysatoren, Lösungsmittel 1

HCID 2631-ButanolLösungsmittel

Versuchsvorschrift

5.7 g (0.02 mol) of sodium 2,4,6-tris(dimethylaminomethyl)phenolate (preparation see Example 19) and 17.9 g of 1-butanol are placed in a 100 ml round-bottomed flask having a magnetic stirrer, and then 3.0 g (0.01 mol) of zinc nitrate are added. The solution is stirred for 45 minutes, and then the precipitated sodium nitrate is filtered off. A clear, dark-brown 25% accelerator solution of zinc bis(2,4,6-tris(dimethylaminomethyl)phenolate) in 1-butanol is obtained.

Aufarbeitung

  1. filtrationthe precipitated sodium nitrate is filtered off

Quellen und Nachweise

ORD-Eintrag
ord-84797d69747b48feb9ddba0a2e545334
Quelldatensatz
uspto-grants-1995_11
Patentnummer
US05470896

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