HuagongsheHuagongshe Chemie-Druckbericht · Nur für Forschungszwecke
4-Tert-Butylaniline → HCID 11184221, Verbindung
Beteiligte Stoffe
| Rolle | Name | HCID | Einwaage |
|---|---|---|---|
| Edukt | 4-Tert-Butylaniline | HCID 69861 | — |
| Edukt | Potassium Bromide | HCID 253877 | — |
| Edukt | Nitrilooxonium tetrafluoroborate | HCID 11137142 | — |
| Lösungsmittel | Acetonitrile | HCID 6342 | — |
| Lösungsmittel | Dichloromethane | HCID 6344 | — |
| Produkt | HCID 11184221 | HCID 11184221 | 78% |
Reaktionsschritte
The 4-tert-butylaniline was dissolved in a 1:1 mixture of acetonitrile and dry methylene chloride prior to addition to the nitrosonium tetrafluoroborate. Yield: 78%. MP 91° C. IR (KBr) 3364.8, 3107.3, 2968.6, 2277.2, 1579.2, 1482.0, 1418.0, 1373.5, 1269.8, 1056.9, 841.1, 544.6, 621.4 cm−1. 1H NMR (400 MHz, CD3CN) δ 8.16 (ABq, J=9.0 Hz, Δv=298.7 Hz, 4H), 1.30 (s, 12H). 13C NMR (100 MHz, CD3CN) δ 168.85, 133.67, 130.43, 111.88, 37.86, 30.84.
Herkunft & Nachweise
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patentnummer | US07384815B2 |
| Quelldatensatz | uspto-grants-2008_06 |
| ORD ID | ord-bde4a78e629a447c9d030bbda46436df |
| Quellennotiz | uspto-grants-2008_06 |