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HRID131079

反应详情

EQUATION

反应方程式

HRID 131079 的结构方程式

REACTANTS

反应物

3
结构：CC(C)(C)c1ccc(N)cc1
HCID69861

4-tert-Butylaniline

C10H15N

结构：[Br-].[K+]
HCID253877

Potassium bromide

BrK

结构：F[B-](F)(F)F.N#[O+]
HCID11137142

未命名化合物

PRODUCTS

生成物

1
结构：CC(C)(C)c1ccc([N+]#N)cc1.F[B-](F)(F)F
HCID11184221

未命名化合物

收率 78%

AUXILIARIES

试剂、催化剂与溶剂

2
结构：CC#N
溶剂HCID6342

Acetonitrile

C2H3N

结构：ClCCl
溶剂HCID6344

Dichloromethane

CH2Cl2

PROCEDURE

实验过程

The 4-tert-butylaniline was dissolved in a 1:1 mixture of acetonitrile and dry methylene chloride prior to addition to the nitrosonium tetrafluoroborate. Yield: 78%. MP 91° C. IR (KBr) 3364.8, 3107.3, 2968.6, 2277.2, 1579.2, 1482.0, 1418.0, 1373.5, 1269.8, 1056.9, 841.1, 544.6, 621.4 cm−1. 1H NMR (400 MHz, CD3CN) δ 8.16 (ABq, J=9.0 Hz, Δv=298.7 Hz, 4H), 1.30 (s, 12H). 13C NMR (100 MHz, CD3CN) δ 168.85, 133.67, 130.43, 111.88, 37.86, 30.84.