Methanol → HCID 11608505, Verbindung

HRID 1375225Notizen

Reaktionsgleichung

Reaktionsgleichung von HRID 1375225
CO.[CH3:3][O:4][C:5]1[CH:10]=[C:9]([C@H:11]2[C@H:16]([N+:17]([O-:19])=[O:18])[CH2:15][CH:14]=[CH:13][CH2:12]2)[CH:8]=[CH:7][C:6]=1[OH:20]>[Pd]>[CH3:3][O:4][C:5]1[CH:10]=[C:9]([C@@H:11]2[CH2:12][CH2:13][CH2:14][CH2:15][C@H:16]2[N+:17]([O-:19])=[O:18])[CH:8]=[CH:7][C:6]=1[OH:20]

Komponenten

4

Edukt 2

HCID 887MethanolHCID 11615748HCID 11615748, Verbindung

Produkt 1

HCID 11608505HCID 11608505, Verbindung

Reagenzien, Katalysatoren, Lösungsmittel 1

HCID 23938PalladiumKatalysator

Versuchsvorschrift

lin 300 ml methanol 8.4 g (33.7 mmol) of trans-2-methoxy-4-(6-nitro-cyclohex-3-enyl)-phenol are solved. To this solution 500 mg of 10% Pd/C are added. The mixture is hydrogenated at room temperature for 6 hours. The mixture was then filtered through Filter Cel and evaporation of the filtrate in vacuum, yielding trans-2 methoxy-4-(2-nitro-cyclohexyl)-phenol as a light yellow solid.

Aufarbeitung

  1. filtrationThe mixture was then filtered
  2. filtrationthrough Filter
  3. customCel and evaporation of the filtrate in vacuum

Quellen und Nachweise

ORD-Eintrag
ord-7f2705ea44f94342a2dc7d26c6485ed3
Quelldatensatz
uspto-grants-2007_01
Patentnummer
US07166746B2

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