Triphenylphosphine → allyl (1S,5R,6S)-6-[1(R)-allyloxycarbonyloxy-ethyl]-1-methyl-2-[3-methyl-2,2-dioxo-5-(2-triethylsilanyloxy-ethyl)-2,3-dihydro-2-thia-1,3-diaza-phenalen-1-ylmethyl]-carbapen-2-em-3-carboxylate

Reaktionsgleichung

[CH2:1]([O:4][C:5]([O:7][C@@H:8]([C@H:10]1[C:25](=[O:26])[N:12]2[C:13]([C:19]([O:21][CH2:22][CH:23]=[CH2:24])=[O:20])=[C:14]([CH2:17]O)[C@H:15]([CH3:16])[C@H:11]12)[CH3:9])=[O:6])[CH:2]=[CH2:3].[C:27]1(P(C2C=CC=CC=2)C2C=CC=CC=2)C=CC=CC=1.[O:46]=[S:47]1(=[O:70])[NH:58][C:57]2[C:59]3[C:53]([CH:54]=[C:55]([CH2:60][CH2:61][O:62][Si:63]([CH2:68][CH3:69])([CH2:66][CH3:67])[CH2:64][CH3:65])[CH:56]=2)=[CH:52][CH:51]=[CH:50][C:49]=3[NH:48]1.N(C(OC(C)C)=O)=NC(OC(C)C)=O>O1CCCC1.C(Cl)(Cl)Cl>[CH2:1]([O:4][C:5]([O:7][C@@H:8]([C@H:10]1[C:25](=[O:26])[N:12]2[C:13]([C:19]([O:21][CH2:22][CH:23]=[CH2:24])=[O:20])=[C:14]([CH2:17][N:48]3[C:49]4=[C:59]5[C:53](=[CH:52][CH:51]=[CH:50]4)[CH:54]=[C:55]([CH2:60][CH2:61][O:62][Si:63]([CH2:66][CH3:67])([CH2:64][CH3:65])[CH2:68][CH3:69])[CH:56]=[C:57]5[N:58]([CH3:27])[S:47]3(=[O:46])=[O:70])[C@H:15]([CH3:16])[C@H:11]12)[CH3:9])=[O:6])[CH:2]=[CH2:3]