Water → Bis(diphenylmethyl) ether

HRID 1388240Notizen

Reaktionsgleichung

Reaktionsgleichung von HRID 1388240
Cl[CH:2]([C:9]1[CH:14]=[CH:13][CH:12]=[CH:11][CH:10]=1)[C:3]1[CH:8]=[CH:7][CH:6]=[CH:5][CH:4]=1.[OH2:15]>>[CH:2]([O:15][CH:2]([C:3]1[CH:8]=[CH:7][CH:6]=[CH:5][CH:4]=1)[C:9]1[CH:14]=[CH:13][CH:12]=[CH:11][CH:10]=1)([C:9]1[CH:14]=[CH:13][CH:12]=[CH:11][CH:10]=1)[C:3]1[CH:8]=[CH:7][CH:6]=[CH:5][CH:4]=1

Komponenten

3

Edukt 2

HCID 962Water2×HCID 7035Chlorodiphenylmethane

Produkt 1

HCID 11323Bis(diphenylmethyl) ether

Versuchsvorschrift

A mixture of 37 g of chlorodiphenylmethane and 100 ml of water were refluxed under nitrogen for 16 hours. After cooling the water was decanted and 40 ml of ethanol was added to induce crystallization. The yellow solid was recrystallized 3 times from ethanol to give 21.9 g of dibenzhydryl ether, m.p. 108°-110°.

Aufarbeitung

  1. temperaturewere refluxed under nitrogen for 16 hours
  2. customwas decanted
  3. addition40 ml of ethanol was added
  4. customcrystallization
  5. customThe yellow solid was recrystallized 3 times from ethanol

Quellen und Nachweise

ORD-Eintrag
ord-de8082e424634f9590c5c2ee70d0ae06
Quelldatensatz
uspto-grants-1984_02
Patentnummer
US04431497

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