Allyl bromide → N,N-Dimethyl-N-(prop-2-en-1-yl)octadecan-1-aminium chloride

HRID 1388870

Reaktionsgleichung

Reaktionsgleichung von HRID 1388870
[CH3:1][N:2]([CH3:21])[CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH2:18][CH2:19][CH3:20].[CH2:22]([Cl:25])[CH:23]=[CH2:24].C(Br)C=C.C(=O)(O)[O-].[Na+]>C(O)(C)C>[Cl-:25].[CH2:22]([N+:2]([CH3:1])([CH3:21])[CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH2:18][CH2:19][CH3:20])[CH:23]=[CH2:24]

Komponenten

6

Edukt 4

HCID 7841Allyl bromideHCID 7850Allyl chlorideHCID 15365DimethyloctadecylamineHCID 516892Sodium Bicarbonate

Produkt 1

HCID 20468836N,N-Dimethyl-N-(prop-2-en-1-yl)octadecan-1-aminium chloride

Reagenzien, Katalysatoren, Lösungsmittel 1

HCID 3776IsopropanolLösungsmittel

Versuchsvorschrift

A 2-liter reaction vessel equipped with a mechanical stirrer and a reflux condenser was charged with 660.0 gm. dimethyl octadecyl amine, 199.0 gm. (2.19 mol) allyl chloride, 13.3 (0.11 mol) gm. allyl bromide, 20 gm. sodium bicarbonate, and 350 ml. isopropyl alcohol. This mixture was heated under reflux overnight. Analyses of a filtered aliquot indicated the reaction was complete. The mixture was filtered and upon analysis had an Effective gram MW of 496.74.

Aufarbeitung

  1. customA 2-liter reaction vessel
  2. customequipped with a mechanical stirrer and a reflux condenser
  3. additionwas charged with 660.0 gm
  4. temperatureThis mixture was heated
  5. temperatureunder reflux overnight
  6. filtrationThe mixture was filtered and upon analysis

Quellen und Nachweise

ORD-Eintrag
ord-31c201d1fc7b4a01b6dd2e904ca8cfbe
Quelldatensatz
uspto-grants-1984_02
Patentnummer
US04434076

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