HCID 86599752, Verbindung → HCID 86599753, Verbindung
Reaktionsgleichung
C(OC([NH:11][C@H:12]1[CH2:17][CH2:16][CH2:15][N:14]([P:18]([NH:27][C:28]2[CH:33]=[CH:32][CH:31]=[CH:30][CH:29]=2)([NH:20][C:21]2[CH:26]=[CH:25][CH:24]=[CH:23][CH:22]=2)=[O:19])[C:13]1=[O:34])=O)C1C=CC=CC=1>CO.[Pd]>[NH2:11][C@H:12]1[CH2:17][CH2:16][CH2:15][N:14]([P:18]([NH:27][C:28]2[CH:33]=[CH:32][CH:31]=[CH:30][CH:29]=2)([NH:20][C:21]2[CH:26]=[CH:25][CH:24]=[CH:23][CH:22]=2)=[O:19])[C:13]1=[O:34]Komponenten
4
Reagenzien, Katalysatoren, Lösungsmittel 2
Versuchsvorschrift
Palladium black (20 mg) was added to a solution of (3S)-3-benzyloxycarbonylamino-1-bis(phenylamino)phosphinyl-2-piperidone (200.2 mg, 0.4184 mmol) in methanol (4 mL), and the resulting mixture was stirred overnight at room temperature under a hydrogen atmosphere.