Sodium Methoxide → HCID 178493296, Verbindung

HRID 1395554

Reaktionsgleichung

Reaktionsgleichung von HRID 1395554
[CH:1]([N:4]([CH:18]([CH3:20])[CH3:19])[CH2:5][CH2:6][NH:7][C:8]1[CH:13]=[C:12]([N+]([O-])=O)[CH:11]=[CH:10][N+:9]=1[O-:17])([CH3:3])[CH3:2].[CH3:21][O-:22].[Na+]>CO>[CH:1]([N:4]([CH:18]([CH3:20])[CH3:19])[CH2:5][CH2:6][NH:7][C:8]1[CH:13]=[C:12]([O:22][CH3:21])[CH:11]=[CH:10][N+:9]=1[O-:17])([CH3:3])[CH3:2]

Komponenten

4

Edukt 2

HCID 10942334Sodium MethoxideHCID 178457399HCID 178457399, Verbindung

Produkt 1

HCID 178493296HCID 178493296, Verbindung

Reagenzien, Katalysatoren, Lösungsmittel 1

HCID 887MethanolLösungsmittel

Versuchsvorschrift

2-(2-Diisopropylaminoethylamino)-4-nitropyridine-N-oxide (10.0 g., 35.5 mmole) is added to a solution of sodium methoxide (3.0 g., 55 mmole) in dry methanol (100 ml.) and refluxed for 4 hours. The solvent is evaporated and the residue dissolved in chloroform, washed with water, dried over sodium sulfate and evaporated to give oily product.

Aufarbeitung

  1. temperaturerefluxed for 4 hours
  2. customThe solvent is evaporated
  3. dissolutionthe residue dissolved in chloroform
  4. washwashed with water
  5. dry with materialdried over sodium sulfate
  6. customevaporated
  7. customto give oily product

Quellen und Nachweise

ORD-Eintrag
ord-36d8a0ae002e49b9beada766ba3a8b0e
Quelldatensatz
uspto-grants-1980_05
Patentnummer
US04203988

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