2-(2,6-Dinitrophenylamino)ethanol → HCID 23362032, Verbindung

HRID 1398934Notizen

Reaktionsgleichung

Reaktionsgleichung von HRID 1398934
[N+:1]([C:4]1[CH:9]=[CH:8][CH:7]=[C:6]([N+:10]([O-])=O)[C:5]=1[NH:13][CH2:14][CH2:15][OH:16])([O-])=O>[Pd].O1CCCC1>[NH2:1][C:4]1[CH:9]=[CH:8][CH:7]=[C:6]([NH2:10])[C:5]=1[NH:13][CH2:14][CH2:15][OH:16]

Komponenten

4

Edukt 1

HCID 233620182-(2,6-Dinitrophenylamino)ethanol

Produkt 1

HCID 23362032HCID 23362032, VerbindungAusbeute 89 %

Reagenzien, Katalysatoren, Lösungsmittel 2

HCID 23938PalladiumKatalysatorHCID 8028TetrahydrofuranLösungsmittel

Versuchsvorschrift

Under hydrogen gas atmosphere, a mixture of 2-[(2,6-dinitrophenyl)amino]ethanol (5.54 g, 24.4 mmol) and 10% palladium on carbon (50% wet, 1.1 g) in tetrahydrofuran (240 mL) was stirred at room temperature for 2 h. The reaction mixture was filtered and concentrated in vacuo to give the title compound as a brown oil (3.63 g, 21.7 mmol, 89%).

Aufarbeitung

  1. filtrationThe reaction mixture was filtered
  2. concentrationconcentrated in vacuo

Quellen und Nachweise

ORD-Eintrag
ord-b048dc9fd0c946ee98d0beb40350427f
Quelldatensatz
uspto-grants-2014_12
Patentnummer
US08901141B2

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