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Methyl Methacrylate → Diethyl carbonate ethylene carbonate

HRID 1402620
Notizen
Druckvorschau

Reaktionsgleichung

Reaktionsgleichung von HRID 1402620
C(OC)(=O)C(C)=C.C(OCC1(CC)COC1)(=O)C(C)=C.C(OCC1CCC2OC2C1)(=O)C=C.[C:34]1(=[O:39])[O:38][CH2:37][CH2:36][O:35]1.[C:40](=[O:47])([O:44][CH2:45][CH3:46])[O:41][CH2:42][CH3:43]>>[C:34]1(=[O:39])[O:38][CH2:37][CH2:36][O:35]1.[C:40](=[O:47])([O:44][CH2:45][CH3:46])[O:41][CH2:42][CH3:43]
KomponentenReaktionsbedingungenVersuchsvorschriftAufarbeitungQuellen und NachweiseNotizen zur Reaktion

Komponenten

6

Edukt 5

HCID 6658Methyl MethacrylateHCID 7303Ethylene carbonateHCID 7766Diethyl CarbonateHCID 11159706(3-Ethyloxetan-3-yl)methyl 2-methylprop-2-enoateHCID 12860205(3,4-Epoxycyclohexyl)methyl Acrylate (stabilized with HQ)

Produkt 1

HCID 66954576Diethyl carbonate ethylene carbonate

Reaktionsbedingungen

Temperatur
40 °C

Versuchsvorschrift

60.0 g of methyl methacrylate, 16.0 g of 3-ethyl-3-oxetanylmethyl methacrylate, 4.0 g of 3,4-epoxycyclohexylmethyl acrylate, 226.6 g of ethylene carbonate and 0.15 g of N,N′-azobisisobutyronitrile were placed in a three-necked flask equipped with a reflux condenser, and mixed for 30 minutes under stirring while introducing nitrogen gas. Temperature was elevated to 70° C. to conduct radical polymerization for 8 hours. The reaction mixture thus obtained was cooled to 40° C. 226.6 g of diethyl carbonate and 0.15 g of N,N′-azobisisobutyronitrile were added to the reaction mixture, and the resulting mixture was again heated to 70° C. to further conduct radical polymerization for 8 hours. The reaction mixture thus obtained was cooled to 40° C. to obtain an ethylene carbonate/diethyl carbonate mixed solvent solution (concentration: 15% by weight) of the crosslinkable polymer B.

Aufarbeitung

  1. customequipped with a reflux condenser
  2. additionmixed for 30 minutes
  3. additionwhile introducing nitrogen gas
  4. customwas elevated to 70° C.
  5. custompolymerization for 8 hours
  6. customThe reaction mixture thus obtained
  7. temperaturethe resulting mixture was again heated to 70° C. to further conduct radical polymerization for 8 hours
  8. customThe reaction mixture thus obtained
  9. temperaturewas cooled to 40° C.

Quellen und Nachweise

ORD-Eintrag
ord-17390a15b9e9460c997083e9c4f8cf4e
Quelldatensatz
uspto-grants-2014_12
DOI
10.6084/m9.figshare.5104873.v1
Patentnummer
US08911648B2

Notizen zur Reaktion

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