8-Methylnon-2-yn-1-ol → 8-Methylnon-2-ynal
Reaktionsgleichung
[CH3:1][CH:2]([CH3:11])[CH2:3][CH2:4][CH2:5][CH2:6][C:7]#[C:8][CH2:9][OH:10]>[O-2].[O-2].[Mn+4].CCOCC>[CH3:1][CH:2]([CH3:11])[CH2:3][CH2:4][CH2:5][CH2:6][C:7]#[C:8][CH:9]=[O:10]Komponenten
4
Reagenzien, Katalysatoren, Lösungsmittel 2
Versuchsvorschrift
Oxidation of 8-methylnon-2yn-1-ol with manganese dioxide in refluxing ether gave 8-methylnon-2yn-1-al. The aldehyde was converted to acetals using appropriate acidic catalysts.
Quellen und Nachweise
- ORD-Eintrag
- ord-6955ae336402451abef24f0d5bc7f1bd
- Quelldatensatz
- uspto-grants-1977_01
- Patentnummer
- US04001454
Notizen zur Reaktion
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