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Benzyl methacrylate → 1-Ethoxyethyl methacrylate (1-ethyl-3-oxacyclobutyl)methyl methacrylate benzyl methacrylate

HRID 1425628
Notizen
Druckvorschau

Reaktionsgleichung

Reaktionsgleichung von HRID 1425628
[C:1]([O:6][CH:7]([O:9][CH2:10][CH3:11])[CH3:8])(=[O:5])[C:2]([CH3:4])=[CH2:3].[C:12]([O:17][CH2:18][C:19]1([CH2:23][CH3:24])[CH2:22][O:21][CH2:20]1)(=[O:16])[C:13]([CH3:15])=[CH2:14].[C:25]([O:30][CH2:31][C:32]1[CH:37]=[CH:36][CH:35]=[CH:34][CH:33]=1)(=[O:29])[C:26]([CH3:28])=[CH2:27].N(C(C)(CC)C([O-])=O)=NC(C)(CC)C([O-])=O>CCCCCCC.C(C(C)=O)C(C)C>[C:1]([O:6][CH:7]([O:9][CH2:10][CH3:11])[CH3:8])(=[O:5])[C:2]([CH3:4])=[CH2:3].[C:12]([O:17][CH2:18][C:19]1([CH2:23][CH3:24])[CH2:20][O:21][CH2:22]1)(=[O:16])[C:13]([CH3:15])=[CH2:14].[C:25]([O:30][CH2:31][C:32]1[CH:33]=[CH:34][CH:35]=[CH:36][CH:37]=1)(=[O:29])[C:26]([CH3:28])=[CH2:27]
KomponentenVersuchsvorschriftAufarbeitungQuellen und NachweiseNotizen zur Reaktion

Komponenten

7

Edukt 4

HCID 17236Benzyl methacrylateHCID 11159706(3-Ethyloxetan-3-yl)methyl 2-methylprop-2-enoateHCID 201933451-Ethoxyethyl Methacrylate (stabilized with MEHQ)HCID 219175032,2'-Azobis(methyl 2-methylpropanate)

Produkt 1

HCID 866432131-Ethoxyethyl methacrylate (1-ethyl-3-oxacyclobutyl)methyl methacrylate benzyl methacrylate

Reagenzien, Katalysatoren, Lösungsmittel 2

HCID 7909Methyl Isobutyl KetoneLösungsmittelHCID 8900HeptaneLösungsmittel

Versuchsvorschrift

Into a 500 ml-volume three-neck flask, 47.5 g (0.3 mol) of 1-ethoxyethyl methacrylate, 33.2 g (0.18 mol) of (1-ethyl-3-oxacyclobutyl)methyl methacrylate, 21.2 g (0.12 mol) of benzyl methacrylate and 300 ml of methyl isobutyl ketone were charged. A catalytic amount of 2,2′-azobis(methyl 2-methylpropionate) was added thereto as a radical polymerization initiator, and polymerization was allowed to proceed at 80° C. for 6 hours in a nitrogen stream. The reaction solution was cooled and then poured in a large amount of heptane to precipitate a polymer. The crystal was collected by filtration and dissolved in diethylene glycol dimethyl ether, and heptane and methyl isobutyl ketone contained in the solution were removed by distillation under reduced pressure to obtain Polymer A-8 (1-ethoxyethyl methacrylate/(1-ethyl-3-oxacyclobutyl)methyl methacrylate/benzyl methacrylate) as a diethylene glycol dimethyl ether solution.

Aufarbeitung

  1. customas a radical polymerization initiator, and polymerization
  2. temperatureThe reaction solution was cooled
  3. customto precipitate a polymer
  4. filtrationThe crystal was collected by filtration
  5. dissolutiondissolved in diethylene glycol dimethyl ether
  6. customwere removed by distillation under reduced pressure

Quellen und Nachweise

ORD-Eintrag
ord-ba4619f136d54d39a7f9ce801a19c2df
Quelldatensatz
uspto-grants-2015_01
DOI
10.6084/m9.figshare.5104873.v1
Patentnummer
US08932800B2

Notizen zur Reaktion

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