1-Bromo-2-nitrobenzene → HCID 23087148, Verbindung

HRID 1433864

Reaktionsgleichung

Reaktionsgleichung von HRID 1433864
Br[C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][C:3]=1[N+:8]([O-:10])=[O:9].C([Sn](CCCC)(CCCC)C1C=CC=CC=1[N+]([O-])=O)CCC.FC(F)(F)S(O[C:39]1[CH2:48][CH2:47][C:46]2[C:41](=[CH:42][CH:43]=[C:44]([O:49][CH3:50])[CH:45]=2)[CH:40]=1)(=O)=O>>[CH3:50][O:49][C:44]1[CH:45]=[C:46]2[C:41]([CH:40]=[C:39]([C:2]3[CH:7]=[CH:6][CH:5]=[CH:4][C:3]=3[N+:8]([O-:10])=[O:9])[CH2:48][CH2:47]2)=[CH:42][CH:43]=1

Komponenten

4

Edukt 3

HCID 113411-Bromo-2-nitrobenzeneHCID 11338886Stannane, tributyl(2-nitrophenyl)-HCID 153302566-Methoxy-3,4-dihydronaphthalen-2-yl trifluoromethanesulfonate

Produkt 1

HCID 23087148HCID 23087148, Verbindung

Versuchsvorschrift

Synthesized from 1-bromo-2-nitrobenzene according to an analogous synthetic method to Preparation Example 76, tributyl(2-nitrophenyl)tin (7.3 g) and 6-methoxy-3,4-dihydronaphthalen-2-yl trifluoromethanesulfonate (2.2 g) were used according to an analogous synthetic method to Preparation Example 77 to provide the title compound (1.5 g).

Aufarbeitung

  1. customwere used according to an analogous synthetic method to Preparation Example 77

Quellen und Nachweise

ORD-Eintrag
ord-b32ce141dc53404ea6e4e18e82ce31b5
Quelldatensatz
uspto-grants-2009_11
Patentnummer
US07612114B2

Verknüpfte Notizen

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