7380-79-2 → HCID 18982460, Verbindung

HRID 1440888Notizen

Reaktionsgleichung

Reaktionsgleichung von HRID 1440888
[CH2:1]([B-:5]([C:18]1[CH:23]=[CH:22][CH:21]=[CH:20][CH:19]=1)([C:12]1[CH:17]=[CH:16][CH:15]=[CH:14][CH:13]=1)[C:6]1[CH:11]=[CH:10][CH:9]=[CH:8][CH:7]=1)[CH2:2][CH2:3][CH3:4].[Li+].[Cl-].[CH3:26][S+:27]([CH3:37])[CH2:28]C(C1C=CC=CC=1)=O>O>[CH3:26][S+:27]([CH3:37])[CH2:28][C:18]1[CH:19]=[CH:20][CH:21]=[CH:22][CH:23]=1.[CH2:1]([B-:5]([C:18]1[CH:23]=[CH:22][CH:21]=[CH:20][CH:19]=1)([C:6]1[CH:7]=[CH:8][CH:9]=[CH:10][CH:11]=1)[C:12]1[CH:17]=[CH:16][CH:15]=[CH:14][CH:13]=1)[CH2:2][CH2:3][CH3:4]

Komponenten

4

Edukt 2

HCID 218810807380-79-2HCID 23668465HCID 23668465, Verbindung

Produkt 1

HCID 18982460HCID 18982460, VerbindungAusbeute 181,8 %

Reagenzien, Katalysatoren, Lösungsmittel 1

HCID 962WaterLösungsmittel2×

Versuchsvorschrift

An aqueous solution of 10.11 g of lithium butyltriphenylborate in 100 ml of water was added to an aqueous solution of 6.24 g of dimethylphenacylsulfonium chloride in 150 ml of water, and the resultant mixture was stirred at room temperature for 30 minutes. The reaction mixture was filtered, and the resultant crystal was washed with water and dried to give 13.58 g of dimethylbenzylsulfonium-butyltriphenylborate as a white crystal.

Aufarbeitung

  1. filtrationThe reaction mixture was filtered
  2. washthe resultant crystal was washed with water
  3. customdried

Quellen und Nachweise

ORD-Eintrag
ord-7fe3501b7f8c4eedb342298a10db1768
Quelldatensatz
uspto-grants-1996_03
Patentnummer
US05500453

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