Ethanol → 3-Ethoxy-5-(2-hydroxyphenyl)-2-cyclohexenone

HRID 1446980Notizen

Reaktionsgleichung

Reaktionsgleichung von HRID 1446980
[OH:1][C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][C:3]=1[CH:8]1[CH2:13][C:12](=[O:14])[CH2:11][C:10](=[O:15])[CH2:9]1.O.[CH2:17](O)[CH3:18]>>[CH2:17]([O:14][C:12]1[CH2:13][CH:8]([C:3]2[CH:4]=[CH:5][CH:6]=[CH:7][C:2]=2[OH:1])[CH2:9][C:10](=[O:15])[CH:11]=1)[CH3:18]

Komponenten

4

Edukt 3

HCID 702EthanolHCID 962WaterHCID 176065765-(2-Hydroxyphenyl)cyclohexane-1,3-dione

Produkt 1

HCID 205521353-Ethoxy-5-(2-hydroxyphenyl)-2-cyclohexenone

Versuchsvorschrift

5-(2-Hydroxyphenyl)-1,3-cyclohexanedione (5.0 g) was dissolved in ethanol (225 ml). The solution was heated under reflux for 3h and diluted to 2 l. by the addition of water. The solid which separated out was collected by filtration, washed with water and dried. Recrystallisation from ethanol afforded the title compound (1.5 g) as pale yellow prisms m.p. 194°-197°.

Aufarbeitung

  1. temperatureThe solution was heated
  2. additiondiluted to 2 l
  3. customThe solid which separated out
  4. filtrationwas collected by filtration
  5. washwashed with water
  6. customdried
  7. customRecrystallisation from ethanol

Quellen und Nachweise

ORD-Eintrag
ord-169f25352850496cae9791a9bef394ff
Quelldatensatz
uspto-grants-1982_02
Patentnummer
US04315006

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