Phenylmercuric Acetate → Phenyl acetate

HRID 1447207

Reaktionsgleichung

Reaktionsgleichung von HRID 1447207
CC(O[Hg]C1C=CC=CC=1)=O.[C:12]([O:15][C:16]1[CH:21]=[CH:20][CH:19]=[CH:18][CH:17]=1)(=[O:14])[CH3:13].C(OI=O)(=O)C>C(O)(=O)C>[C:12]([O:15][C:16]1[CH:21]=[CH:20][CH:19]=[CH:18][CH:17]=1)(=[O:14])[CH3:13]

Komponenten

4

Edukt 2

HCID 16682730Phenylmercuric AcetateHCID 86738254Phenyl iodoso diacetate

Produkt 1

HCID 31229Phenyl acetate

Reagenzien, Katalysatoren, Lösungsmittel 1

HCID 176Acetic AcidLösungsmittel

Versuchsvorschrift

The procedure of Example 3 is repeated except that only 10 ml. of acetic acid is charged to the reaction vessel, thereby increasing the concentration of the phenyl mercuric acetate and phenyl iodoso diacetate reactants in the liquid. At the end of the 0.25 hour of reaction at 120° C., phenyl acetate yield is found to be increased to 68%, at a phenyl mercuric acetate conversion of about 72% and a phenyl acetate selectivity of about 94%.

Aufarbeitung

  1. customAt the end of the 0.25 hour of reaction at 120° C.

Quellen und Nachweise

ORD-Eintrag
ord-a28dddae7f5f4de8b751370c240c3100
Quelldatensatz
uspto-grants-1982_02
Patentnummer
US04316046

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