Biphenyl → Silane, trichloro(9H-fluoren-9-ylmethyl)-

HRID 1457371

Reaktionsgleichung

Reaktionsgleichung von HRID 1457371
[Al].[C:2]1([C:8]2[CH:13]=[CH:12][CH:11]=[CH:10][CH:9]=2)[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=1.Cl[CH:15]([Si:18]([Cl:21])([Cl:20])[Cl:19])[CH2:16]Cl>CCCCCC>[Cl:19][Si:18]([CH2:15][CH:16]1[C:13]2[CH:12]=[CH:11][CH:10]=[CH:9][C:8]=2[C:2]2[C:7]1=[CH:6][CH:5]=[CH:4][CH:3]=2)([Cl:21])[Cl:20]

Komponenten

5

Edukt 3

HCID 7095BiphenylHCID 79093Silane, trichloro(1,2-dichloroethyl)-HCID 5359268Aluminum

Produkt 1

HCID 12065632Silane, trichloro(9H-fluoren-9-ylmethyl)-Ausbeute 38,9 %

Reagenzien, Katalysatoren, Lösungsmittel 1

HCID 8058HexaneLösungsmittel2×

Versuchsvorschrift

In a 250 ml, three-necked, frame dried, round bottom flask, aluminum 0.40 g (15 mmol), biphenyl 20.0 g (130 mmol), and (1,2-dichloroethyl)- trichlorosilane 7.50 ml (53.5 mmol) were reacted as in Example 1 at 120° C. for 30 min. Freshly distilled hexane (60 ml) was added to the reaction mixture and insoluble solids in hexane were filtered from the organic solution. After hexane was distilled, the reaction products were vacuum distilled to give 6.53 g of 9-(trichlorosilyl)methylfluorene (bp; 130°-135° C./0.2 torr, yield; 18%).

Aufarbeitung

  1. customIn a 250 ml, three-necked, frame dried
  2. filtrationwere filtered from the organic solution
  3. distillationAfter hexane was distilled
  4. distillationdistilled

Quellen und Nachweise

ORD-Eintrag
ord-8c55fb26c72747aeb7123249a869ebe3
Quelldatensatz
uspto-grants-1998_12
Patentnummer
US05847182

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