2H-1,2,4-Oxadiazin-3(4H)-one, dihydro-5-thioxo- → HCID 178442899, Verbindung

HRID 1462197Notizen

Reaktionsgleichung

Reaktionsgleichung von HRID 1462197
[O:1]1[CH2:6][C:5](=S)[NH:4][C:3](=[O:8])[NH:2]1.[CH2:9]([NH2:27])[CH2:10][CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][CH2:16]/[CH:17]=[CH:18]\[CH2:19][CH2:20][CH2:21][CH2:22][CH2:23][CH2:24][CH2:25][CH3:26]>>[CH2:9]([NH:27][C:5]1[CH2:6][O:1][NH:2][C:3](=[O:8])[N:4]=1)[CH2:10][CH2:11][CH:12]=[CH:13][CH2:14][CH2:15][CH2:16][CH2:17][CH2:18][CH2:19][CH2:20][CH2:21][CH2:22][CH2:23][CH2:24][CH2:25][CH3:26]

Komponenten

3

Edukt 2

HCID 30069082H-1,2,4-Oxadiazin-3(4H)-one, dihydro-5-thioxo-HCID 5356789Oleylamine

Produkt 1

HCID 178442899HCID 178442899, VerbindungAusbeute 16,4 %

Versuchsvorschrift

To 0.66 g (0.005 mole) of 6H-1,2,4-oxadiazin-3(2H)-one-5(4H)-thione dissolved in 10 ml of freshly distilled dry dioxane is added 1.33 g (0.0051 mole) of oleylamine. The reaction mixture is stirred for 17 hours at room temperature and the crystalline material filtered, washed with additional dry dioxane and chloroform, and dried to give 0.3 g (16 percent) of 5-(4-octadecenylamino)-6H-1,2,4-oxadiazin-3(2H)-one.

Aufarbeitung

  1. distillationof freshly distilled dry dioxane
  2. filtrationthe crystalline material filtered
  3. washwashed with additional dry dioxane and chloroform
  4. customdried

Quellen und Nachweise

ORD-Eintrag
ord-f780cc7bcec741a1980ac2d72229e5d4
Quelldatensatz
uspto-grants-1984_07
Patentnummer
US04459403

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