Hydrochloric Acid → HCID 20441742, Verbindung

HRID 1463074

Reaktionsgleichung

Reaktionsgleichung von HRID 1463074
Cl[C:2]1[CH:7]=[CH:6][C:5]([S:8]([OH:11])(=[O:10])=O)=[CH:4][C:3]=1[N+:12]([O-:14])=[O:13].[NH2:15][C:16]1[CH:21]=[CH:20][CH:19]=[CH:18][CH:17]=1.[ClH:22]>CC(N(C)C)=O>[N+:12]([C:3]1[CH:4]=[C:5]([S:8]([Cl:22])(=[O:10])=[O:11])[CH:6]=[CH:7][C:2]=1[NH:15][C:16]1[CH:21]=[CH:20][CH:19]=[CH:18][CH:17]=1)([O-:14])=[O:13]

Komponenten

5

Edukt 3

HCID 313Hydrochloric AcidHCID 6115AnilineHCID 67132Benzenesulfonic acid, 4-chloro-3-nitro-

Produkt 1

HCID 20441742HCID 20441742, Verbindung

Reagenzien, Katalysatoren, Lösungsmittel 1

HCID 31374DimethylacetamideLösungsmittel

Versuchsvorschrift

A mixture composed of 23.8 g (0.1 mol) of 4-chloro-3-nitrobenzenesulfonic acid, 28 g of aniline and 30 ml of dimethylacetamide was heated to 90° to 100° C. for 3 hours. After being allowed to cool, the reaction solution was poured into cold diluted hydrochloric acid, and the resulting yellow crystals were filtered off. The resulting salt of 3-nitro-4-phenylaminobenzenesulfonic acid was chlorinated under the same condition as in (1-b) to obtain 3-nitro-4-phenylaminobenzenesulfonyl chloride (3-b).

Aufarbeitung

  1. temperaturewas heated to 90° to 100° C. for 3 hours
  2. temperatureto cool
  3. filtrationthe resulting yellow crystals were filtered off

Quellen und Nachweise

ORD-Eintrag
ord-b3c4b2856bed44d09a757626ce51b855
Quelldatensatz
uspto-grants-1984_07
Patentnummer
US04463079

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