Isoamyl Nitrite → 2-Methyl-4-nitrosoresorcinol

HRID 1464416

Reaktionsgleichung

Reaktionsgleichung von HRID 1464416
[CH3:1][C:2]1[C:8]([OH:9])=[CH:7][CH:6]=[CH:5][C:3]=1[OH:4].[OH-].[K+].[N:12](OCCC(C)C)=[O:13]>C(O)C>[CH3:1][C:2]1[C:8]([OH:9])=[C:7]([N:12]=[O:13])[CH:6]=[CH:5][C:3]=1[OH:4]

Komponenten

5

Edukt 3

HCID 8053Isoamyl NitriteHCID 118432-MethylresorcinolHCID 14797Potassium Hydroxide

Produkt 1

HCID 1006162-Methyl-4-nitrosoresorcinol

Reagenzien, Katalysatoren, Lösungsmittel 1

HCID 702EthanolLösungsmittel

Versuchsvorschrift

19.8 g. 2-Methylresorcinol and 13.4 g. potassium hydroxide are dissolved in 120 ml. ethanol and cooled to 5° C. 24 ml. Isopentyl nitrite are added dropwise thereto, the reaction mixture is stirred for 3 hours and the precipitate is filtered off with suction. The yellow solid material is stirred into 200 ml. 5N sulphuric acid, the bright yellow product thereby precipitating out. Yield 22 g.

Aufarbeitung

  1. filtrationthe precipitate is filtered off with suction
  2. stirringThe yellow solid material is stirred into 200 ml
  3. custom5N sulphuric acid, the bright yellow product thereby precipitating out

Quellen und Nachweise

ORD-Eintrag
ord-63c2a46ced484bca92e3fbc8bb0f2b1c
Quelldatensatz
uspto-grants-1994_04
Patentnummer
US05304645

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