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Potassium Carbonate → 1-(2-Fluoro-5-methylpyridin-3-YL)-N-(pyrimidin-4-YL)isoquinoline-6-sulfonamide

HRID 1473595
Notizen
Druckvorschau

Reaktionsgleichung

Reaktionsgleichung von HRID 1473595
Cl[C:2]1[C:11]2[C:6](=[CH:7][C:8]([S:12]([NH:15][C:16]3[CH:21]=[CH:20][N:19]=[CH:18][N:17]=3)(=[O:14])=[O:13])=[CH:9][CH:10]=2)[CH:5]=[CH:4][N:3]=1.[F:22][C:23]1[C:28](B(O)O)=[CH:27][C:26]([CH3:32])=[CH:25][N:24]=1.C(=O)([O-])[O-].[K+].[K+].B(O)O>O.C1C=CC([P]([Pd]([P](C2C=CC=CC=2)(C2C=CC=CC=2)C2C=CC=CC=2)([P](C2C=CC=CC=2)(C2C=CC=CC=2)C2C=CC=CC=2)[P](C2C=CC=CC=2)(C2C=CC=CC=2)C2C=CC=CC=2)(C2C=CC=CC=2)C2C=CC=CC=2)=CC=1.O1CCOCC1>[F:22][C:23]1[C:28]([C:2]2[C:11]3[C:6](=[CH:7][C:8]([S:12]([NH:15][C:16]4[CH:21]=[CH:20][N:19]=[CH:18][N:17]=4)(=[O:14])=[O:13])=[CH:9][CH:10]=3)[CH:5]=[CH:4][N:3]=2)=[CH:27][C:26]([CH3:32])=[CH:25][N:24]=1
KomponentenReaktionsbedingungenVersuchsvorschriftAufarbeitungQuellen und NachweiseNotizen zur Reaktion

Komponenten

8

Edukt 4

HCID 11430Potassium CarbonateHCID 61668Boronic Acid2×HCID 447548582-Fluoro-5-methylpyridine-3-boronic acidHCID 866876591-chloro-N-(pyrimidin-4-yl)isoquinoline-6-sulfonamide

Produkt 1

HCID 866876581-(2-Fluoro-5-methylpyridin-3-YL)-N-(pyrimidin-4-YL)isoquinoline-6-sulfonamideAusbeute 27 %

Reagenzien, Katalysatoren, Lösungsmittel 3

HCID 178418397HCID 178418397, VerbindungKatalysator2×HCID 962WaterLösungsmittel2×HCID 312751,4-DioxaneLösungsmittel

Reaktionsbedingungen

Temperatur
120 °C

Versuchsvorschrift

To a microwave vial charged with 1-chloro-N-(pyrimidin-4-yl)isoquinoline-6-sulfonamide (Intermediate GG; 3.00 g, 9.35 mmol), 2-fluoro-5-picoline-3-boronic acid (1.469 ml, 12.16 mmol), potassium carbonate (6.46 g, 46.8 mmol) and Pd(Ph3P)4 (1.081 g, 0.935 mmol) was added Dioxane (46.8 ml) and Water (15.59 ml) and heated thermally to 120° C. After 3 hrs LC-MS indicated about 40% conversion with starting material present. Additional boronic acid was added (1 g) and heating continued at 120° C. for 4 hrs affording ˜75% conversion. The mixture was allowed to stir at room temperature over the 3 days under nitrogen afford little to no further conversion. Additional boronic acid (500 mg) and Pd(PPh3)4 (500 mg) was added and the mixture heated back to 120° C. for 3 hr affording near complete conversion according to LC-MS. The mixture was cooled to room temperature, transferred to a seperatory funnel, diluted with water and extracted with EtOAc but the material stayed in the aqueous phase, although this wash did remove many impurities (including PPh3O). The aqueous was washed with DCM, but again the material stuck in the aqueous phase. The aqueous was acidified to ˜pH 2 affording a precipitate which was collected as a brown solid, fairly clean product by LC-MS (300 mg). The aqueous was dried to near dryness affording a precipitate which was collected but was mostly salts with some product. The solid and filtrate were combined and silica gel added and the mixture dried under reduced pressure. The material was purified with a 100 g ultra snap column ramping MeOH in DCM (0-50%) affording product (only 400 mg) as a light yellow solid. Much of the material had remained on the dry pack. The dry packed slurry was purified 2× (split into two parts) by loading directly onto a KP-C18-HS 60 g Biotage column using the reverse phase MPLC ramping IPA in H2O (with 1% NH4OH) (0-100%) affording 1 g of product as a brown solid, in total (1.4 g, 38%). m/z (ESI) 396.2 (M+H)+

Aufarbeitung

  1. temperatureheating
  2. waitcontinued at 120° C. for 4 hrs
  3. customaffording ˜75% conversion
  4. customafford little to no further conversion
  5. temperaturethe mixture heated back to 120° C. for 3 hr
  6. customaffording near complete conversion
  7. temperatureThe mixture was cooled to room temperature
  8. customtransferred to a seperatory funnel
  9. extractionextracted with EtOAc
  10. customdid remove many impurities (including PPh3O)
  11. washThe aqueous was washed with DCM
  12. customaffording a precipitate which
  13. customwas collected as a brown solid, fairly clean product by LC-MS (300 mg)
  14. customThe aqueous was dried
  15. customaffording a precipitate which
  16. customwas collected
  17. additionsilica gel added
  18. customthe mixture dried under reduced pressure
  19. customThe material was purified with a 100 g ultra snap column
  20. customaffording product (only 400 mg) as a light yellow solid
  21. customwas purified
  22. custom2× (split into two parts) by loading directly onto a KP-C18-HS 60 g Biotage column

Quellen und Nachweise

ORD-Eintrag
ord-876f5b964bfc40aaafa8af9484766e89
Quelldatensatz
uspto-grants-2015_04
DOI
10.6084/m9.figshare.5104873.v1
Patentnummer
US09012443B2

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