1-(Triisopropylsilyl)indole → HCID 11395451, Verbindung
Reaktionsgleichung
CC(C)[Si](C(C)C)(C(C)C)n1ccc2ccccc21>B1Oc2ccccc2O1.CC(C)(O)C(C)(C)O.CCN(CC)CC.Cc1ccccc1.Fc1c(F)c(F)c(B(c2c(F)c(F)c(F)c(F)c2F)c2c(F)c(F)c(F)c(F)c2F)c(F)c1F>CC(C)[Si](C(C)C)(C(C)C)n1cc(B2OC(C)(C)C(C)(C)O2)c2ccccc21Komponenten
7
Edukt 1
Produkt 1
Reagenzien, Katalysatoren, Lösungsmittel 5
Reaktionsbedingungen
- Temperatur
- 120 °C
Versuchsvorschrift
Prepared from N-(triisopropylsilyl)-1H-indole (4a, 54.7 mg, 0.200 mmol, 1.00 equiv) and catBH (96.0 mg, 0.800 mmol, 4.00 equiv) according to GP 2. The title compound was purified by flash column chromatography using cyclohexane/EtOAc/Et3N (30/1/1) as eluent to afford 6a (50.3 mg, 63%) as a slightly yellow oil.
Quellen und Nachweise
- ORD-Eintrag
- ord-60618b7fc5b54d599ac4309f26d5cb76
- Quelldatensatz
- Borylation dataset from Roche
Notizen zur Reaktion
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