1-Hexene → 5-Decene

HRID 1522936

Reaktionsgleichung

Reaktionsgleichung von HRID 1522936
C=CCCCC.[CH3:7][CH2:8][CH2:9][CH2:10]/[CH:11]=[CH:12]\[CH2:13][CH2:14][CH2:15][CH3:16]>>[CH3:7][CH2:8][CH2:9][CH2:10][CH:11]=[CH:12][CH2:13][CH2:14][CH2:15][CH3:16]

Komponenten

3

Edukt 2

HCID 115971-HexeneHCID 5364449Cis-5-Decene

Produkt 1

HCID 239165-Decene

Versuchsvorschrift

After the reaction was cooled to room temperature, the mixture was filtered through a 100 mL silica gel plug with hexanes to remove the metal complex. The filtrate was dried via rotavap to remove the solvent and also the substrate, 1-hexene, affording the product as colorless liquid. The scale of a typical reaction was 5 mL of the substrate, 1-hexene. (Z)-5-decene: 1H NMR (500 MHz, CDCl3) δ 5.38 (m, 2, CH), 2.06 (m, 4, CH2), 1.35 (m, 8, CH2), 0.93 (m, 6, CH3); 13C NMR (125 MHz, CDCl3) δ 130.06, 32.31, 27.21, 22.66, 14.33.

Aufarbeitung

  1. customThe scale of a typical reaction

Quellen und Nachweise

ORD-Eintrag
ord-7e6c833563ca4f7da0861baa1c196af9
Quelldatensatz
uspto-grants-2015_07
Patentnummer
US09079173B2

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