Dichloromethane → HCID 131733156, Verbindung

HRID 1525795Notizen

Reaktionsgleichung

Reaktionsgleichung von HRID 1525795
[CH2:1]([C:16]1[CH:22]=[CH:21][C:19]([NH2:20])=[CH:18][CH:17]=1)[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][CH2:13][CH2:14][CH3:15].[C:23](=[O:26])([O-])[O-:24].[K+].[K+].Cl[CH2:30]Cl>ClC(OC)=O.O>[CH3:30][O:24][C:23](=[O:26])[NH:20][C:19]1[CH:18]=[CH:17][C:16]([CH2:1][CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][CH2:13][CH2:14][CH3:15])=[CH:22][CH:21]=1

Komponenten

6

Edukt 3

HCID 6344DichloromethaneHCID 11430Potassium CarbonateHCID 713745384-Pentadecylaniline

Produkt 1

HCID 131733156HCID 131733156, Verbindung

Reagenzien, Katalysatoren, Lösungsmittel 2

HCID 962WaterLösungsmittel2×HCID 6586Methyl chloroformateLösungsmittel

Versuchsvorschrift

To the solution of 4-pentadecanylaniline (3.4 g) in dichloromethane (60 mL), methyl chloroformate (1.1 mL) and the solution of potassium carbonate (7.8 g) in water (110 mL) were added at 0° C., followed by stirring at room temperature for 14 hours. The reaction solution was poured to water, followed by extraction with dichloroethane. The organic layer was washed sequentially with 2N hydrochloric acid, water and an aqueous saturated sodium chloride solution, and dried with anhydrous magnesium sulfate. The reaction solution was concentrated under reduced pressure to obtain the title compound (3.9 g) having the following physical property values.

Aufarbeitung

  1. extractionfollowed by extraction with dichloroethane
  2. washThe organic layer was washed sequentially with 2N hydrochloric acid, water
  3. dry with materialan aqueous saturated sodium chloride solution, and dried with anhydrous magnesium sulfate
  4. concentrationThe reaction solution was concentrated under reduced pressure

Quellen und Nachweise

ORD-Eintrag
ord-13fd395f19c3494abcaa9807e6014fc5
Quelldatensatz
uspto-grants-2015_07
Patentnummer
US09085523B2

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