Hydrochloric Acid → antimony (V) decanethiol

HRID 1577067

Reaktionsgleichung

Reaktionsgleichung von HRID 1577067
[Sb:1](=O)([O-])([O-])[O-].[Na+].[Na+].[Na+].[Sb].[CH2:10]([SH:20])[CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH2:18][CH3:19].Cl>O>[CH2:10]([SH:20])[CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH2:18][CH3:19].[Sb+5:1]

Komponenten

6

Edukt 4

HCID 313Hydrochloric AcidHCID 89171-DecanethiolHCID 25469Antimonic acid, sodium saltHCID 5354495Antimony

Produkt 1

HCID 86737980antimony (V) decanethiol

Reagenzien, Katalysatoren, Lösungsmittel 1

HCID 962WaterLösungsmittel

Reaktionsbedingungen

Temperatur
4 °C

Versuchsvorschrift

Sodium antimonate obtained from U.S. Antimony Corporation (9.49 g, 0.02347 mole) was placed in a reaction vessel and 1-decanethiol from Eastman Kodak (50 ml, 0.2347 mole) added and stirred. Concentrated hydrochloric acid (3.9 ml, 0.0468 mole) was added dropwise and an immediate temperature increase of 4° C. was observed. The mixture was heated and the byproduct of the reaction, water, was distilled over at 28° C. and a vacuum of 50 mm Hg. After 2.5 hours 45.57 g of antimony (V) decanethiol was obtained. The product was filtered to remove unreacted sodium antimonate and the additional byproduct of the reaction, sodium chloride.

Aufarbeitung

  1. temperatureThe mixture was heated
  2. distillationwas distilled over at 28° C.

Quellen und Nachweise

ORD-Eintrag
ord-c01b6090979e444dbe4c074b43123026
Quelldatensatz
uspto-grants-1981_09
Patentnummer
US04287118

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