Bromine → HCID 21567566, Verbindung

HRID 1579168Notizen

Reaktionsgleichung

Reaktionsgleichung von HRID 1579168
[C:1]([NH:5][NH:6][C:7]1([C:15]#[N:16])[CH2:14][CH2:13][CH2:12][CH2:11][CH2:10][CH2:9][CH2:8]1)([CH3:4])([CH3:3])[CH3:2].BrBr.C(NNC(C#N)(C1CC1)C)(C)(C)C>>[C:1]([N:5]=[N:6][C:7]1([C:15]#[N:16])[CH2:14][CH2:13][CH2:12][CH2:11][CH2:10][CH2:9][CH2:8]1)([CH3:4])([CH3:2])[CH3:3]

Komponenten

4

Edukt 3

HCID 24408BromineHCID 21567553HCID 21567553, VerbindungHCID 23344788HCID 23344788, Verbindung

Produkt 1

HCID 21567566HCID 21567566, Verbindung

Versuchsvorschrift

1-t-Butylazo-1-cyanocyclooctane was prepared in 93% crude yield by oxidizing 1-t-butylhydrazo-1-cyanocyclooctane with bromine using the same procedure described in Example XIIIC for the oxidation of 1-t-butylhydrazo-1-cyano-1-cyclopropylethane. The crude product was chromatographed over alumina and the product eluted with pentane. The infrared spectrum of the purified product was consistent with the structure of the desired azo. The compound has a 10 hour half-life in trichlorobenzene at approximately 55°C.

Aufarbeitung

  1. customThe crude product was chromatographed over alumina
  2. washthe product eluted with pentane
  3. customat approximately 55°C.

Quellen und Nachweise

ORD-Eintrag
ord-95b94a0eba6743728f8e1cf34313af2e
Quelldatensatz
uspto-grants-1976_01
Patentnummer
US03931143

Notizen zur Reaktion

Wird geladen…