Bromine → HCID 21567580, Verbindung

HRID 1579170Notizen

Reaktionsgleichung

Reaktionsgleichung von HRID 1579170
[C:1]([NH:5][NH:6][C:7]1([C:14]#[N:15])[CH2:13][CH2:12][CH2:11][CH2:10][CH2:9][CH2:8]1)([CH3:4])([CH3:3])[CH3:2].BrBr.C(NNC(C#N)(C1CC1)C)(C)(C)C>>[C:1]([N:5]=[N:6][C:7]1([C:14]#[N:15])[CH2:13][CH2:12][CH2:11][CH2:10][CH2:9][CH2:8]1)([CH3:4])([CH3:2])[CH3:3]

Komponenten

4

Edukt 3

HCID 24408BromineHCID 21567558HCID 21567558, VerbindungHCID 23344788HCID 23344788, Verbindung

Produkt 1

HCID 21567580HCID 21567580, Verbindung

Versuchsvorschrift

1-t-Butylazo-1-cyanocycloheptane was prepared in 100% crude yield by oxidizing 1-t-butylhydrazo-1-cyanocycloheptane with bromine using the same procedure described in Example XIIIC for the oxidation of 1-t-butylhydrazo-1-cyano-1-cyclopropylethane. The crude product was chromatographed over alumina and the product eluted with pentane. The infrared spectrum of the purified product was consistent with the structure of the desired azo. The compound has a 10 hour half-life in trichlorobenzene at approximately 68°C.

Aufarbeitung

  1. customThe crude product was chromatographed over alumina
  2. washthe product eluted with pentane
  3. customat approximately 68°C.

Quellen und Nachweise

ORD-Eintrag
ord-452db6448fa142be9b0c1d9f0f65a949
Quelldatensatz
uspto-grants-1976_01
Patentnummer
US03931143

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