Furan, 2,2'-[oxybis(methylene)]bis- → 2-{[(Furan-2-yl)methoxy]methyl}-5-methylfuran

HRID 1579232Notizen

Reaktionsgleichung

Reaktionsgleichung von HRID 1579232
[CH2:1]([O:7][CH2:8][C:9]1[O:13][CH:12]=[CH:11][CH:10]=1)[C:2]1[O:6][CH:5]=[CH:4][CH:3]=1.[CH3:14]C1OC(CBr)=CC=1.C(Br)C1OC=CC=1>CCOCC>[CH2:8]([O:7][CH2:1][C:2]1[O:6][C:5]([CH3:14])=[CH:4][CH:3]=1)[C:9]1[O:13][CH:12]=[CH:11][CH:10]=1

Komponenten

5

Edukt 3

HCID 263034Furan, 2,2'-[oxybis(methylene)]bis-HCID 46037652-(Bromomethyl)furanHCID 122459262-(Bromomethyl)-5-methylfuran

Produkt 1

HCID 205603562-{[(Furan-2-yl)methoxy]methyl}-5-methylfuran

Reagenzien, Katalysatoren, Lösungsmittel 1

HCID 3283Diethyl EtherLösungsmittel

Versuchsvorschrift

d. 5-Methyl-furfuryl furfuryl ether is prepared by the procedure described by J. E. Zanetti in J.Am.Chem.Soc. 49, 1066 (1927) for the difurfuryl ether, starting with 5-methyl-furfuryl bromide (Compt, Rend. 222, 1441 (1946) instead of furfuryl bromide of Zanetti. The product was isolated by ether extraction of the crude mixture after having diluted with water. For purification the ether extract was distilled twice -- b.p. 68°-70°C. at 0.01 mm./Hg vacuum. The product was a viscous colourless liquid, darkening rapidly on contact with air.

Quellen und Nachweise

ORD-Eintrag
ord-d86a43e285094528879b7fe296798f3b
Quelldatensatz
uspto-grants-1976_01
Patentnummer
US03931166

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