Cycloocta-1,3-diene → 2,7-Bis(trichlorosilyl)-1-octene

HRID 1583095

Reaktionsgleichung

[CH:1]1[CH2:8][CH2:7][CH2:6][CH2:5][CH:4]=[CH:3][CH:2]=1.[Cl:9][SiH:10]([Cl:12])[Cl:11]>[Cl-].C([P+](CCCC)(CCCC)CCCC)CCC>[Cl:9][Si:10]([Cl:12])([Cl:11])[C:2]([CH2:3][CH2:4][CH2:5][CH2:6][CH:7]([Si:10]([Cl:12])([Cl:11])[Cl:9])[CH3:8])=[CH2:1]

Komponenten

Reaktionsbedingungen

Temperatur: 180 °C

Versuchsvorschrift

As in Example 1, 1,3-cyclooctadiene (1.00 g, 9.24 mmol), trichlorosilane (5.01 g, 36.99 mmol) and tetrabutylphosphonium chloride (0.27 g, 0.92 mmol) were added in a 25 mL stainless steel tube under nitrogen atmosphere. After sealing the cylinder with a cap, the reactor was maintained at 180° C. for 20 hours. The resulting mixture was distilled to yield 0.35 g (yield: 10%) of 2,7-bis(trichlorosilyl)-1-octene.

Aufarbeitung

distillationThe resulting mixture was distilled

Quellen und Nachweise

ORD-Eintrag: ord-1795d9348a6f4ea0a0d9b85ebfc52834
Quelldatensatz: uspto-grants-2004_05
DOI: 10.6084/m9.figshare.5104873.v1
Patentnummer: US06740766B2

Verknüpfte Notizen

Wird geladen…