Reaktionsgleichung
[CH3:1][C:2](=[O:5])[CH2:3][CH3:4].[CH3:6][C:7]([O:14]O)([CH3:13])[CH2:8][C:9]([CH3:12])([CH3:11])[CH3:10].S(=O)(=O)(O)O.[O:21]=[O:22]>CCCCC>[C:7]([O:21][O:22][C:2]([O:5][O:14][C:7]([CH2:8][C:9]([CH3:12])([CH3:11])[CH3:10])([CH3:13])[CH3:6])([CH2:3][CH3:4])[CH3:1])([CH2:8][C:9]([CH3:12])([CH3:11])[CH3:10])([CH3:13])[CH3:6]Komponenten
6
Edukt 4
Produkt 1
Reagenzien, Katalysatoren, Lösungsmittel 1
Reaktionsbedingungen
- Temperatur
- 0 °C
Versuchsvorschrift
To a jacketed reactor was charged 8.36g. (0.116 mole) of 2-butanone, 38.0g. (0.232 mole) of 1,1,3,3-tetramethylbutyl hydroperoxide (89.7% assay) and 100 ml. of pentane. To the vigorously stirred mixture at 0°C was added 17.2g. of 77% sulfuric acid over a period of 15 minutes and the mixture was allowed to stir at 0°C for 4 hours. The product was worked up as in Example I and 23.8g. (59.5% of theory, uncorr.) of liquid was obtained which had an active oxygen content of 8.41% (theory, 9.25%). Hence, the assay of the product was 91.0% and the corrected yield was 54.2%. An infrared spectrum of the product showed no OH or C=O bands but showed a strong and broad OO band centered at 875 cm-1.
Aufarbeitung
- additionTo a jacketed reactor was charged 8.36g
- additionTo the vigorously stirred mixture at 0°C was added 17.2g
- custom(59.5% of theory, uncorr.) of liquid was obtained which
Quellen und Nachweise
- ORD-Eintrag
- ord-33d844cdaf3243aaa62c92809ae3c0f3
- Quelldatensatz
- uspto-grants-1976_04
- Patentnummer
- US03950432
Verknüpfte Notizen
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