Hydrochloric Acid → 5-(3-Methylbutoxy)-2-propylthiophenol

HRID 1606105Notizen

Reaktionsgleichung

Reaktionsgleichung von HRID 1606105
CN(C)C(=O)[S:4][C:5]1[CH:10]=[C:9]([O:11][CH2:12][CH2:13][CH:14]([CH3:16])[CH3:15])[CH:8]=[CH:7][C:6]=1[CH2:17][CH2:18][CH3:19].[OH-].[K+].CNC.Cl>O.C(O)COCCO>[CH3:15][CH:14]([CH3:16])[CH2:13][CH2:12][O:11][C:9]1[CH:8]=[CH:7][C:6]([CH2:17][CH2:18][CH3:19])=[C:5]([SH:4])[CH:10]=1

Komponenten

7

Edukt 4

HCID 313Hydrochloric AcidHCID 674DimethylamineHCID 14797Potassium HydroxideHCID 21545974S-5-(3-methylbutoxy)-2-propylphenyl N,N-dimethylthiocarbamate

Produkt 1

HCID 215459855-(3-Methylbutoxy)-2-propylthiophenol

Reagenzien, Katalysatoren, Lösungsmittel 2

HCID 962WaterLösungsmittelHCID 8117Diethylene GlycolLösungsmittel

Versuchsvorschrift

A solution of 136.1 parts of S-5-(3-methylbutoxy)-2-propylphenyl N,N-dimethylthiocarbamate and 280 parts of potassium hydroxide in 1000 parts of digol was stirred under nitrogen at 120° - 130° for 9 hours, after which no dimethylamine could be detected in the effluent nitrogen. The mixture was cooled, poured into 8000 parts of water and the resulting solution was acidified to pH 1 with hydrochloric acid. The mixture was extracted with ether and the latter was washed with water, dried over magnesium sulphate, filtered and evaporated to dryness to give 95.7 g of the desired product 5-(3-methylbutoxy)-2-propylthiophenol.

Aufarbeitung

  1. temperatureThe mixture was cooled
  2. extractionThe mixture was extracted with ether
  3. washthe latter was washed with water
  4. dry with materialdried over magnesium sulphate
  5. filtrationfiltered
  6. customevaporated to dryness

Quellen und Nachweise

ORD-Eintrag
ord-b1f54d07f00b402ab11bb08dbc9756b0
Quelldatensatz
uspto-grants-1976_04
Patentnummer
US03952013

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