Hydrochloric Acid → N,N-Diethyl-P-phenylenediamine dihydrochloride

HRID 16129

Reaktionsgleichung

Reaktionsgleichung von HRID 16129
[CH2:1]([N:3]([CH2:11][CH3:12])[C:4]1[CH:9]=[CH:8][C:7]([NH2:10])=[CH:6][CH:5]=1)[CH3:2].[ClH:13]>C(OCC)C>[ClH:13].[ClH:13].[CH2:11]([N:3]([CH2:1][CH3:2])[C:4]1[CH:9]=[CH:8][C:7]([NH2:10])=[CH:6][CH:5]=1)[CH3:12]

Komponenten

4

Edukt 2

HCID 313Hydrochloric AcidHCID 7120N,N-Diethyl-p-phenylenediamine

Produkt 1

HCID 19799983N,N-Diethyl-P-phenylenediamine dihydrochlorideAusbeute 100 %

Reagenzien, Katalysatoren, Lösungsmittel 1

HCID 3283Diethyl EtherLösungsmittel

Versuchsvorschrift

N,N-diethyl-p-phenylenediamine (5 g, 30.4 mmol) was dissolved in diethyl ether (25 cm3) and hydrochloric acid (6 cm3, 10 M) was added and the mixture was concentrated to give the title compound (7.22 g, 100%) as a red/brown solid. dH (250 MHz; D2O): 7.68 (4H, m, ArH), 3.69 (4H, q, 7.32, NCH2), 1.11 (6H, t, 7.32, CH3); dC (62.9 MHz; D2O): 12.1 (CH3), 56.4 (NCH2), 126.8 (ArC), 127.6 (ArC), 135.5 (ArC), 139.1 (ArC).

Aufarbeitung

  1. concentrationthe mixture was concentrated

Quellen und Nachweise

ORD-Eintrag
ord-cdcfae7f36ac4516963007566eca95a0
Quelldatensatz
uspto-grants-2010_06
Patentnummer
US07737138B2

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