Benzoyl Peroxide → 1,1'-(3-Bromoprop-1-ene-1,1-diyl)dibenzene

HRID 1614803Notizen

Reaktionsgleichung

Reaktionsgleichung von HRID 1614803
[C:1]1([C:7]([C:10]2[CH:15]=[CH:14][CH:13]=[CH:12][CH:11]=2)=[CH:8][CH3:9])[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1.C(OOC(=O)C1C=CC=CC=1)(=O)C1C=CC=CC=1.[Br:34]N1C(=O)CCC1=O>C(Cl)(Cl)(Cl)Cl>[Br:34][CH2:9][CH:8]=[C:7]([C:10]1[CH:11]=[CH:12][CH:13]=[CH:14][CH:15]=1)[C:1]1[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1

Komponenten

5

Edukt 3

HCID 7187Benzoyl PeroxideHCID 67184N-bromobutanimideHCID 2382071,1-Diphenyl-1-propene

Produkt 1

HCID 123465451,1'-(3-Bromoprop-1-ene-1,1-diyl)dibenzene

Reagenzien, Katalysatoren, Lösungsmittel 1

HCID 5943Carbon TetrachlorideLösungsmittel

Versuchsvorschrift

A mixture of 1,1-diphenyl-1-propene (17.0 g, 0.10 mol), carbon tetrachloride (100 ml), benzoylperoxide (0.2 g) and N-bromosuccinimide (17.8 g, 0.10 mol) was heated at reflux temperature for 18 h. The reaction mixture was allowed to cool to room temperature, filtered and the solvent was evaporated in vacuo to give 3-bromo-1 1-diphenyl-1-propene in a quantitative yield.

Aufarbeitung

  1. temperaturewas heated
  2. temperatureat reflux temperature for 18 h
  3. filtrationfiltered
  4. customthe solvent was evaporated in vacuo

Quellen und Nachweise

ORD-Eintrag
ord-49284c1892f1468eab03279d1f3b0fe0
Quelldatensatz
uspto-grants-1993_03
Patentnummer
US05198451

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