3-Oxaspiro[5.5]undec-7-en-9-one → 3-Oxaspiro[5.5]undecan-9-one

HRID 1615743Notizen

Reaktionsgleichung

Reaktionsgleichung von HRID 1615743
[CH2:1]1[C:6]2([CH2:11][CH2:10][C:9](=[O:12])[CH:8]=[CH:7]2)[CH2:5][CH2:4][O:3][CH2:2]1.[H][H]>C(OCC)(=O)C.[Pd]>[CH2:5]1[C:6]2([CH2:11][CH2:10][C:9](=[O:12])[CH2:8][CH2:7]2)[CH2:1][CH2:2][O:3][CH2:4]1

Komponenten

5

Edukt 2

HCID 687636893-Oxaspiro[5.5]undec-7-en-9-oneHCID 178418361HCID 178418361, Verbindung

Produkt 1

HCID 687657833-Oxaspiro[5.5]undecan-9-one

Reagenzien, Katalysatoren, Lösungsmittel 2

HCID 23938PalladiumKatalysatorHCID 8857Ethyl AcetateLösungsmittel

Versuchsvorschrift

Under a hydrogen atmosphere 1.30 g (7.82 mmol) 3-oxaspiro[5.5]undec-7-en-9-one were hydrogenated with 0.2 g Pd/C (10%) in 15 ml of ethyl acetate at 50° C. and 3 bar hydrogen pressure for three days. The reaction mixture was suction filtered and evaporated down.

Aufarbeitung

  1. filtrationfiltered
  2. customevaporated down

Quellen und Nachweise

ORD-Eintrag
ord-d71340bca72e442c982bd127c0715c99
Quelldatensatz
uspto-grants-2014_07
Patentnummer
US08765763B2

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