Benzoyl Peroxide → HCID 18675872, Verbindung

HRID 1635088Notizen

Reaktionsgleichung

Reaktionsgleichung von HRID 1635088
[Cl:1][C:2]1[CH:7]=[CH:6][N:5]=[C:4]([CH3:8])[C:3]=1[O:9][CH3:10].[Br:11]N1C(=O)CCC1=O.C(OOC(=O)C1C=CC=CC=1)(=O)C1C=CC=CC=1>C(Cl)(Cl)(Cl)Cl>[Cl:1][C:2]1[CH:7]=[CH:6][N:5]=[C:4]([CH2:8][Br:11])[C:3]=1[O:9][CH3:10]

Komponenten

5

Edukt 3

HCID 7187Benzoyl PeroxideHCID 67184N-bromobutanimideHCID 105830464-Chloro-3-methoxy-2-methylpyridine

Produkt 1

HCID 18675872HCID 18675872, Verbindung

Reagenzien, Katalysatoren, Lösungsmittel 1

HCID 5943Carbon TetrachlorideLösungsmittel

Versuchsvorschrift

4-Chloro-3-methoxy-2-methyl-pyridine (6.12 g) is dissolved in carbon tetrachloride (80 ml) then N-bromo-succinimide (7.12 g) and benzoyl peroxide (1 g) are added. The reaction mixture is refluxed under UV irradiation for 1.5 hour. The solid is filtered after cooling and the solvent evaporated. The desired product is purified by chromatography on silica gel.

Aufarbeitung

  1. temperatureThe reaction mixture is refluxed under UV irradiation for 1.5 hour
  2. filtrationThe solid is filtered
  3. temperatureafter cooling
  4. customthe solvent evaporated
  5. customThe desired product is purified by chromatography on silica gel

Quellen und Nachweise

ORD-Eintrag
ord-6591c0c517204113a4c93daf9a5f06cb
Quelldatensatz
uspto-grants-2003_01
Patentnummer
US06509349B1

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