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HuagongsheHuagongshe Chemie-Druckbericht · Nur für Forschungszwecke
HRID 1646100Erstellt: 26. Oktober 2026

4,4'-Dihydroxybiphenyl → 1,1'-Biphenyl, 4,4'-dimethoxy-

https://huagongshe.com/reaction/1646100

Reaktionsgleichung

Beteiligte Stoffe

RolleNameHCIDEinwaage
Edukt4,4'-DihydroxybiphenylHCID 7112—
Edukt4-BromoanisoleHCID 7730—
Edukt4-BromophenolHCID 7808—
Produkt2-Bromobenzoic acidHCID 6940—
Produkt1,1'-Biphenyl, 4,4'-dimethoxy-HCID 1648435%

Reaktionsschritte

However, Busch et al. found that with aromatic compounds containing polar substituents, the selectivity to biphenyls was much lower. For example, p-bromophenol gave ca. 13.4% 4,4'-dihydroxybiphenyl, p-bromoanisole gave ca. 35% 4,4'-dimethoxybiphenyl, bromobenzoic acid gave 40% 4,4'-biphenyldicarboxylic acid and 3-bromobenzoic acid gave 56.5% 3,3'-biphenyldicarboxylic acid.

Herkunft & Nachweise

DOI10.6084/m9.figshare.5104873.v1
PatentnummerUS05177258
Quelldatensatzuspto-grants-1993_01
ORD IDord-6c322c571a7648399c8d3497427d5a68
Quellennotizuspto-grants-1993_01