Hydrochloric Acid → Benzenesulfinic acid

HRID 1648161Notizen

Reaktionsgleichung

Reaktionsgleichung von HRID 1648161
[C:1]1([S:7]([O:9][Na])=[O:8])[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1.N#N.Cl>O>[C:1]1([S:7]([OH:9])=[O:8])[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1

Komponenten

5

Edukt 3

HCID 313Hydrochloric AcidHCID 947NitrogenHCID 178527445HCID 178527445, Verbindung

Produkt 1

HCID 12057Benzenesulfinic acid

Reagenzien, Katalysatoren, Lösungsmittel 1

HCID 962WaterLösungsmittel

Versuchsvorschrift

PhSO2Na (1.6579 g., 0.0101 mol) was dissolved in water (100 mL), while keeping an atmosphere of N2. HCl (12 M, 0.84 mL, 0.0101 mol). was added in order to produce PhSO2H. Benzoquinone (0.01 mol, 1.081 g) was added while flushing with N2. A white to grey precipitate was formed immediately. The solution was stirred for 5 min, filtered (glass sinter no. 3) under N2, washed with distilled water (20 mL) and dried under vacuum (+20C) over night. Yield 2.08 g. The product was identified by 1H- and 13CNMR spectroscopy.

Aufarbeitung

  1. additionwas added in order

Quellen und Nachweise

ORD-Eintrag
ord-6e0750e47e324b62aea92c04c1f254eb
Quelldatensatz
uspto-grants-1995_07
Patentnummer
US05435991

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