Ethylamine → N-ethyl-2,6-dinitro-4-t-butylaniline

Reaktionsgleichung

[CH2:1]([NH2:3])[CH3:2].[N+:4]([C:7]1[CH:12]=[C:11]([C:13]([CH3:16])([CH3:15])[CH3:14])[CH:10]=[C:9]([N+:17]([O-:19])=[O:18])[C:8]=1Cl)([O-:6])=[O:5]>>[CH2:1]([NH:3][C:8]1[C:9]([N+:17]([O-:19])=[O:18])=[CH:10][C:11]([C:13]([CH3:16])([CH3:14])[CH3:15])=[CH:12][C:7]=1[N+:4]([O-:6])=[O:5])[CH3:2]

Komponenten

Edukt 2

HCID 6341Ethylamine

HCID 751764-tert-Butyl-2,6-dinitrochlorobenzene

Produkt 1

HCID 20364246N-ethyl-2,6-dinitro-4-t-butylaniline

Versuchsvorschrift

Following the above procedure, two grams of a 70% aqueous solution of ethylamine was reacted with 2.6 grams (0.01 mole) of 2,6-dinitro-4-t-butylchlorobenzene to yield 2 grams of N-ethyl-2,6-dinitro-4-t-butylaniline as orange needles melting at 70°-73° C.

Quellen und Nachweise

ORD-Eintrag: ord-c51985d4c67b4249b0d167653f0cfac3
Quelldatensatz: uspto-grants-1978_03
DOI: 10.6084/m9.figshare.5104873.v1
Patentnummer: US04077795

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