Acetic Acid → Acetic acid, 2-(4-nitrophenyl)hydrazide

HRID 1679246Notizen

Reaktionsgleichung

Reaktionsgleichung von HRID 1679246
[N+:1]([C:4]1[CH:9]=[CH:8][C:7]([NH:10][NH2:11])=[CH:6][CH:5]=1)([O-:3])=[O:2].[C:12](O)(=[O:14])[CH3:13]>>[C:12]([NH:11][NH:10][C:7]1[CH:6]=[CH:5][C:4]([N+:1]([O-:3])=[O:2])=[CH:9][CH:8]=1)(=[O:14])[CH3:13]

Komponenten

3

Edukt 2

HCID 176Acetic AcidHCID 3310889(4-Nitrophenyl)hydrazine

Produkt 1

HCID 3404344Acetic acid, 2-(4-nitrophenyl)hydrazide

Reaktionsbedingungen

Temperatur
90 °C

Versuchsvorschrift

4-Nitrophenylhydrazine (15.0 g, 0.10 mole) and acetic acid (24.0 g, 0.40 mole) were mixed in a flask equipped with a stirrer and reflux condenser and heated at about 90° C for one hour. The solid mass was collected, washed with water, and then dissolved in hot ethanol. The resulting solution was chilled in ice to give tan needles. Yield 14.4 g (74%), mp 207°-209° C.

Aufarbeitung

  1. customequipped with a stirrer
  2. temperaturereflux condenser
  3. customThe solid mass was collected
  4. washwashed with water
  5. dissolutiondissolved in hot ethanol
  6. temperatureThe resulting solution was chilled in ice
  7. customto give tan needles

Quellen und Nachweise

ORD-Eintrag
ord-dfa883a8947146d0a3519bd8d60be686
Quelldatensatz
uspto-grants-1978_03
Patentnummer
US04080207

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