Palladium Chloride → Palladium triflate

HRID 1682776Notizen

Reaktionsgleichung

Reaktionsgleichung von HRID 1682776
Cl[Pd:2]Cl.[OH:4][S:5]([C:8]([F:11])([F:10])[F:9])(=[O:7])=[O:6]>C(Cl)Cl>[O-:7][S:5]([C:8]([F:11])([F:10])[F:9])(=[O:6])=[O:4].[Pd+2:2].[O-:7][S:5]([C:8]([F:11])([F:10])[F:9])(=[O:6])=[O:4]

Komponenten

4

Edukt 2

HCID 24290Palladium ChlorideHCID 62406Trifluoromethanesulfonic acid

Produkt 1

HCID 11603820Palladium triflate

Reagenzien, Katalysatoren, Lösungsmittel 1

HCID 6344DichloromethaneLösungsmittel

Versuchsvorschrift

PdCl2 (1.0 g, 5.6 mmol) was slurried in CH2Cl2 (20 mL) and triflic acid (1.7 g, 11.3 mmol) was added dropwise. The mixture was stirred at room temperature overnight. The solvent was removed and 0.9 g of rust color solid was collected. 19F NMR (CDCl3): δ-5 78.5.

Aufarbeitung

  1. customThe solvent was removed
  2. custom0.9 g of rust color solid was collected

Quellen und Nachweise

ORD-Eintrag
ord-f53ff08b482544a3899a442bed6f5ef3
Quelldatensatz
uspto-grants-1997_06
Patentnummer
US05635585

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