Cesium carbonate → 2',3',5'-Tris-o-(tert-butyldimethylsilyl)-8-(3-pyridinyl)adenosine

Reaktionsgleichung

[N:1]1[CH:6]=[CH:5][CH:4]=[C:3](B(O)O)[CH:2]=1.C([O-])([O-])=O.[Cs+].[Cs+].Br[C:17]1[N:18]([C:49]2[N:50]=[CH:51][N:52]=[C:53]([NH2:56])[C:54]=2[N:55]=1)[C@@H:19]1[O:48][C@H:38]([CH2:39][O:40][Si:41]([C:44]([CH3:47])([CH3:46])[CH3:45])([CH3:43])[CH3:42])[C@@H:29]([O:30][Si:31]([C:34]([CH3:37])([CH3:36])[CH3:35])([CH3:33])[CH3:32])[C@H:20]1[O:21][Si:22]([C:25]([CH3:28])([CH3:27])[CH3:26])([CH3:24])[CH3:23]>O1CCOCC1.C1C=CC([P]([Pd]([P](C2C=CC=CC=2)(C2C=CC=CC=2)C2C=CC=CC=2)([P](C2C=CC=CC=2)(C2C=CC=CC=2)C2C=CC=CC=2)[P](C2C=CC=CC=2)(C2C=CC=CC=2)C2C=CC=CC=2)(C2C=CC=CC=2)C2C=CC=CC=2)=CC=1.O.CCOC(C)=O>[Si:22]([O:21][C@@H:20]1[C@H:29]([O:30][Si:31]([C:34]([CH3:35])([CH3:36])[CH3:37])([CH3:33])[CH3:32])[C@@H:38]([CH2:39][O:40][Si:41]([C:44]([CH3:45])([CH3:46])[CH3:47])([CH3:42])[CH3:43])[O:48][C@H:19]1[N:18]1[C:49]2[N:50]=[CH:51][N:52]=[C:53]([NH2:56])[C:54]=2[N:55]=[C:17]1[C:3]1[CH:2]=[N:1][CH:6]=[CH:5][CH:4]=1)([C:25]([CH3:27])([CH3:28])[CH3:26])([CH3:23])[CH3:24]