Water → Calcium Chloride Hexahydrate

Temperatur

10 °C

The aqueous filtrate (1000 parts) from a calcium hypochlorite paste filter containing 26.5 percent CaCl2, 1.5 percent Ca(ClO3)2 and minor amounts of Ca(OCl)2 is fed to a heated mixing vessel in which the filtrate is blended with 96 parts of a calcium chlorate containing 45 percent Ca(ClO3)2 and 32 percent CaCl2. During mixing, the solution is heated to its atmospheric boiling point to convert the calcium hypochlorite present to Ca(ClO3)2 and the blended solution fed to an evaporative crystallizer. The solution is evaporatively cooled to a temperature of about 40° C. to produce crystals of calcium chloride tetrahydrate, CaCl2.4H2O. The crystals were separated from a liquor containing about 33 percent CaCl2, 32 percent Ca(ClO3)2 and 37 percent H2O. The calcium chloride tetrahydrate crystals were recovered. The liquor from the evaporative crystallizer was diluted with water to provide a solution containing about 28 percent CaCl2, 27 percent Ca(ClO3)2 and 45 percent water which was fed to a cooling crystallizer. The crystallizer, cooled by refrigeration, maintained the solution at a temperature of about 10° C. Crystals of calcium chloride hexahydrate are formed and separated from a mother liquor containing 37 percent Ca(ClO3)2 and 20 percent CaCl2. The mother liquor is fed to an evaporative crystallizer for the formation and recovery of anhydrous Ca(ClO3)2 crystals from a calcium chlorate liquor by the process of Example 1. The calcium chlorate mother liquor having a weight ratio of Ca(ClO3)2 to CaCl2 of 1.40 is recycled to the mixing vessel.