Methane → HCID 131712825, Verbindung

HRID 1702834

Reaktionsgleichung

Reaktionsgleichung von HRID 1702834
[Cl:1][C:2]1[C:11]([CH3:12])=[N:10][C:9]2[C:4](=[CH:5][CH:6]=[CH:7][CH:8]=2)[N:3]=1.C.[NH2:14][C:15]([NH2:17])=[S:16]>CC(C)=O>[ClH:1].[CH3:12][C:11]1[C:2]([S:16][C:15](=[NH:14])[NH2:17])=[N:3][C:4]2[C:9]([N:10]=1)=[CH:8][CH:7]=[CH:6][CH:5]=2

Komponenten

5

Edukt 3

HCID 297MethaneHCID 2362762-Chloro-3-methylquinoxalineHCID 2723790Thiourea

Produkt 1

HCID 131712825HCID 131712825, Verbindung

Reagenzien, Katalysatoren, Lösungsmittel 1

HCID 180AcetoneLösungsmittel2×

Versuchsvorschrift

2-Chloro-3-methylquinoxaline (10.72 g., 0.06 mole) was dissolved in 150 ml. of acetone, treated with Norit and filtered. The filtrate was added to 4.56 g. (0.06 mole) of thiourea in 150 ml. acetone. The solution was stirred at reflux under nitrogen for 2 hours. The precipitate which began to form after 5 minutes, was filtered while the reaction mixture was hot. The solid was collected, washed with hot acetone and dried to give 11.85 g. of a pink solid, m.p. 156°-157° C.

Aufarbeitung

  1. filtrationfiltered
  2. additionThe filtrate was added to 4.56 g
  3. temperatureat reflux under nitrogen for 2 hours
  4. customto form after 5 minutes
  5. filtrationwas filtered while the reaction mixture
  6. customThe solid was collected
  7. washwashed with hot acetone
  8. customdried
  9. customto give 11.85 g

Quellen und Nachweise

ORD-Eintrag
ord-4f4a18a7a7104b0787f29fc49657dc86
Quelldatensatz
uspto-grants-1982_09
Patentnummer
US04349674

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