4-tert-Butylphenol → Methyl alpha-(p-tert-butylphenoxy)-alpha-[p-(alpha,alpha,alpha-trifluoro-m-tolyloxy)phenyl]acetate

HRID 1704075

Reaktionsgleichung

Reaktionsgleichung von HRID 1704075
Br[CH:2]([C:7]1[CH:12]=[CH:11][C:10]([O:13][C:14]2[CH:15]=[C:16]([C:20]([F:23])([F:22])[F:21])[CH:17]=[CH:18][CH:19]=2)=[CH:9][CH:8]=1)[C:3]([O:5][CH3:6])=[O:4].[C:24]([C:28]1[CH:33]=[CH:32][C:31]([OH:34])=[CH:30][CH:29]=1)([CH3:27])([CH3:26])[CH3:25]>>[C:24]([C:28]1[CH:29]=[CH:30][C:31]([O:34][CH:2]([C:7]2[CH:12]=[CH:11][C:10]([O:13][C:14]3[CH:15]=[C:16]([C:20]([F:23])([F:22])[F:21])[CH:17]=[CH:18][CH:19]=3)=[CH:9][CH:8]=2)[C:3]([O:5][CH3:6])=[O:4])=[CH:32][CH:33]=1)([CH3:27])([CH3:25])[CH3:26]

Komponenten

3

Edukt 2

HCID 73934-tert-ButylphenolHCID 20392575Methyl alpha-bromo-alpha-[p-(alpha,alpha,alpha-trifluoro-m-tolyloxy)phenyl]acetate

Produkt 1

HCID 12531890Methyl alpha-(p-tert-butylphenoxy)-alpha-[p-(alpha,alpha,alpha-trifluoro-m-tolyloxy)phenyl]acetateAusbeute 73,5 %

Versuchsvorschrift

In a manner similar to Example 16, 7.62 g of methyl α-bromo-α-[p-(α,α,α-trifluoro-m-tolyloxy)phenyl]acetate was reacted with 3.75 g of p-tert-butylphenol to give 6.6 g of product as an amber oil.

Quellen und Nachweise

ORD-Eintrag
ord-82936600eeca489caf1b00509222193d
Quelldatensatz
uspto-grants-1978_11
Patentnummer
US04125729

Verknüpfte Notizen

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