Aluminum(III) Chloride → cis-2-(3-Methyl-1-oxo-2-butenyl)cyclopentanecarboxylic acid
Reaktionsgleichung
[Cl-].[Al+3].[Cl-].[Cl-].[C@@H:5]12[C:13](=[O:14])[O:12][C:10](=[O:11])[C@@H:6]1[CH2:7][CH2:8][CH2:9]2>ClCCCl>[CH3:9][C:5]([CH3:13])=[CH:6][C:10]([C@H:6]1[CH2:7][CH2:8][CH2:9][C@H:5]1[C:13]([OH:12])=[O:14])=[O:11]Komponenten
4
Edukt 2
Produkt 1
Reagenzien, Katalysatoren, Lösungsmittel 1
Versuchsvorschrift
To a stirred suspension of 4.38 g. (32.86 mmole) of anhydrous aluminum chloride in 100 ml. of 1,2-dichloroethane at room temperature is added 2.30 g. (16.43 mmoles) of cis-1,2-cyclopentanedicarboxylic anhydride. Ethylene is then bubbled through the clear solution with stirring for four hours.
Aufarbeitung
- additionTo a stirred suspension of 4.38 g
- customEthylene is then bubbled through the clear solution
Quellen und Nachweise
- ORD-Eintrag
- ord-3522fd64688e4d348c58640434f43a2d
- Quelldatensatz
- uspto-grants-1980_06
- Patentnummer
- US04206137
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