N-(3-(dimethylamino)propyl)formamide → N,N-dimethyl-N-(5-nitro-1-naphthylmethyl)-N-3-formamidopropylammonium chloride

HRID 1706108

Reaktionsgleichung

Reaktionsgleichung von HRID 1706108
[CH3:1][N:2]([CH3:9])[CH2:3][CH2:4][CH2:5][NH:6][CH:7]=[O:8].[N+:10]([C:13]1[CH:22]=[CH:21][CH:20]=[C:19]2[C:14]=1[CH:15]=[CH:16][CH:17]=[C:18]2[CH2:23][Cl:24])([O-:12])=[O:11]>O>[Cl-:24].[CH3:1][N+:2]([CH3:9])([CH2:23][C:18]1[C:19]2[C:14](=[C:13]([N+:10]([O-:12])=[O:11])[CH:22]=[CH:21][CH:20]=2)[CH:15]=[CH:16][CH:17]=1)[CH2:3][CH2:4][CH2:5][NH:6][CH:7]=[O:8]

Komponenten

4

Edukt 2

HCID 80020N-(3-(dimethylamino)propyl)formamideHCID 2260471-Chloromethyl-5-nitronaphthalene

Produkt 1

HCID 86733015N,N-dimethyl-N-(5-nitro-1-naphthylmethyl)-N-3-formamidopropylammonium chloride

Reagenzien, Katalysatoren, Lösungsmittel 1

HCID 962WaterLösungsmittel

Versuchsvorschrift

Proceeding in a manner similar to that described above in B-8a, 29.9 parts of N-(3-dimethylaminopropyl)formamide and 44.3 parts of 5-nitro-1-chloromethylnaphthalene were interacted in 30 parts of water to obtain N,N-dimethyl-N-(5-nitro-1-naphthylmethyl)-N-3-formamidopropylammonium chloride. The product was not isolated but was used directly in solution for reduction of the nitro group.

Quellen und Nachweise

ORD-Eintrag
ord-46675f4e4ec642f88db6e000b9a4188c
Quelldatensatz
uspto-grants-1980_06
Patentnummer
US04206144

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