Water → p-Tetradecyloxyphenylacetic acid

HRID 1728834Notizen

Reaktionsgleichung

Reaktionsgleichung von HRID 1728834
C[O:2][C:3](=[O:26])[CH2:4][C:5]1[CH:10]=[CH:9][C:8]([O:11][CH2:12][CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH2:18][CH2:19][CH2:20][CH2:21][CH2:22][CH2:23][CH2:24][CH3:25])=[CH:7][CH:6]=1.[OH-].[K+].O>C(O)C>[CH2:12]([O:11][C:8]1[CH:9]=[CH:10][C:5]([CH2:4][C:3]([OH:26])=[O:2])=[CH:6][CH:7]=1)[CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH2:18][CH2:19][CH2:20][CH2:21][CH2:22][CH2:23][CH2:24][CH3:25]

Komponenten

5

Edukt 3

HCID 962WaterHCID 14797Potassium HydroxideHCID 10316608[4-(Tetradecyloxy)phenyl]acetic acid methyl ester

Produkt 1

HCID 10472964p-Tetradecyloxyphenylacetic acidAusbeute 84,1 %

Reagenzien, Katalysatoren, Lösungsmittel 1

HCID 702EthanolLösungsmittel

Versuchsvorschrift

The title compound is prepared by the procedure of Example 32 using 75 g of product from Example 51, 34.8 g of potassium hydroxide, 45 ml of water and 800 ml of ethyl alcohol. The residue is recrystallized from carbon tetrachloride/hexane to give 60.6 g of the desired product as white crystals.

Aufarbeitung

  1. customThe residue is recrystallized from carbon tetrachloride/hexane

Quellen und Nachweise

ORD-Eintrag
ord-3fa2c6f9b4054134a76a4e45faae10a4
Quelldatensatz
uspto-grants-1994_07
Patentnummer
US05328921

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